Temperature Effects on Neodymium Iron Boron, NdFeB, magnets

1. Ndfeb 52
2. Ndfeb Cte
3. Ndfeb Density

Compression Ndfeb magnets are widely used in micro motors: rain brush motor, step motors, CD-ROM, DVD and Walkman & Vibration motors of the mobile phone etc. Other applications include brushless motor, speaker, buzzers and toys, printer, air-conditioners, refrigerators. Please Contact Us to buy magnets Permanent Plastic Bonded NdFeB Magnets. Applied Magnets Rare Earth Neodymium Magnets (also known as Neo, NdFeB, or Super Magnets) are: Magnetized axially through the thickness with poles on the long flat surfaces. STRONG - Grade N42 Magnetic Energy, stronger than N40, N38, N35, and much stronger than the strongest ceramic magnet.

The NdFeB magnets are the strongest magnets available on the market. Up to +150 degrees

C, they are stronger than the other rare earth magnet, SmCo. At around +150 degrees C and above, the performance of these Neodymium magnets is not as good as that of SmCo. The maximum recommended temperature for the NdFeB magnets is +230 degrees C, whereas the SmCo can work at +300 to +350 degrees C.

NdFeB can be used in low-temperature environment. But at around 135 Kelvin (-138 degrees C), the direction of magnetization is said to change from a single axis (easy-axis) to an easy-cone which could cause a fall in output of up to 15% due to this spin reorientation. It is possible to use Neodymium Iron Boron magnets to be used at even colder temperatures but this drop in output will need to be taken into account.

The influence of magnetoelastic effects on the anisotropy in NdFeB permanent magnets has been investigated. A relation between the magnetostriction coefficients and the magnetoelastic anisotropy is derived for crystals with tetragonal symmetry. Product Name: Sintered Neodymium Iron Boron (NdFeB) Permanent Magnet SECTION 2 - HAZARDOUS INGREDIENTS Chemical Name: Sintered Neodymium Iron Boron (NdFeB) Permanent Magnet Material or Component Weight% CAS No. ACGUH TLV (mg/m3) Notes Neodymium 33% 7440-00-8 Not established Iron 65% 7439-89-6 10 (oxide).

The temperature coefficient of Intrinsic Coercivity (how Hci varies with temperature), b, for Neodymium is approximately -0.6%/degree C (from ambient, but a range of -0.45%/degree C to -0.6%/degree C is possible depending on the Neodymium grade) between +20 and +120 degrees C.

The temperature coefficient of Remanent Induction (how Br varies with temperature), a, for Neodymium is -0.12%/degree C (from ambient, but a range of -0.08%/degree C to -0.12%/degree C is possible depending on the Neodymium grade).

It should be noted that, strictly speaking, these values for a and b actually change with temperature and the use of stated values from 20 to 120 degrees C may result in inaccuracies in design (actual BH curves at temperatures assist in clarifying for design purposes).

Temperature characteristics of NdFeB grades

Elevated temperatures have three effects. A reversible loss is when the output falls with temperature but returns as it cools down (the temperature coefficients reflect this e.g. a twenty degree C rise above ambient causes a drop in magnetic output of N42 of around 20 x 0.12 = 2.4%, which recovers when the temperature returns down to ambient). An irreversible but recoverable loss occurs when the output falls but does not return when the magnet cools down (e.g. the high temperature takes the Intrinsic working point beyond the knee of the Intrinsic curve, causing demagnetization) but this would be recovered if the Neodymium magnet is remagnetized. For all extents and purposes, this output is lost because the magnet will not be remagnetized during practical application but will demagnetize again if a remagnetized magnet is re-used in the same application (the heat will demagnetize the Neodymium magnet again – the magnetic circuit would have to be improved to fix this problem). When cooled, such a demagnetized magnet will have the original HCI but a lower Br (the Br will have increased by the reversible temperature coefficient amount applied to the reduced high-temperature Br). An irreversible irrecoverable loss is due to the high temperature causing a permanent structural change in the magnet as is usually because the magnet has been taken far beyond its working temperature. The damage is permanent and remagnetizing will not bring the performance back again. If an irreversible but recoverable loss occurs, the magnet is said to be thermally stabilized. If the cooled Neodymium magnet is taken back up to temperature, no further irreversible losses will occur – the only loss is the temporary drop in output due to the reversible losses (a function of the temperature coefficients). By being thermally stabilized, the Neodymium magnetic performance is better predicted even if the drop in output has occurred due to an irreversible but recoverable loss. Some applications may require this thermal stabilization which is usually done by taking to a temperature a few degrees C above the required maximum operating temperature but it may also be performed by applying a demagnetising pulse (this replicates the process by taking the Intrinsic curve beyond the knee of the Intrinsic curve but requires knowing by how much the magnets would demagnetise by through raised temperature but cannot take into account BH curve waveshape variations so has an element of inaccuracy at all times).

It is also generally advised against subjecting magnets to thermal shock (i.e. putting a cold magnet onto an extremely hot surface) as too high a thermal shock could cause the magnets to break.

How grade choice affects performance when the NdFeB magnet is subjected to heat

It is possible to demagnetize a Neodymium magnet by applying an external magnetic field in a direction opposite to the direction of magnetization (DoM) of the NdFeB magnet. The extent of demagnetization is a function of the total magnetic circuit (and hence the Intrinsic working point), the temperature (and hence the actual BH curve shape for the NdFeB in use) and the magnitude of the externally applied demagnetizing field. If the Intrinsic working point if known, a line is drawn on the BH curve from the origin (B=0, H=0) to the Intrinsic working point is drawn (this is the Intrinsic Load Line). If the magnitude of the externally applied demagnetizing field is known (Ha), the Intrinsic Load Line is translated along so the start of the load line has moved from H=0 to H=Ha. The slope of the load line is the same but the working point in the Intrinsic curve has moved. If the new Intrinsic working point has not entered the region of the ‘knee’ of the Intrinsic curve, the demagnetization of the magnet is minimal, possibly so little it cannot be measured. When the external field is removed, the Intrinsic working point ‘recoils’ back but at a slope equal to the Intrinsic curve slope where H=0 and B=Br. If the Intrinsic working point had entered the region of the ‘knee’, the recoil does not follow the original BH curve shape – a new BH curve shape is produced which has a lower new Br (this is the effect of demagnetization). Applying an external field again up to the same magnitude of the original Ha has no further demagnetizing effect – only if Ha exceeds the original Ha will further demagnetization be seen. If the Ha equals Hc (the coercive force), the Neodymium magnet will appear to have no magnetic output whilst the field is applied but removing the field will have caused potentially very high demagnetization. But if Ha equals Hci (the Intrinsic coercive force, when Ha is removed, the Neodymium magnet will be totally demagnetized (i.e. it will show no magnetic performance). To minimize the effects of externally applied fields, higher HCI rated Neodymium magnets may be used and the design can be improved to give a better Intrinsic Load Line (also known as a higher PCI or Intrinsic Permeance Coefficient, where Pci=Pc+1 and Pc is the Permeance Coefficient based on using the Normal Curve). Where possible a lower operating temperature for the application may also assist (this is unlikely to be designed in though).

How a magnet is demagnetized by applying an external magnetic field

For note, the effects of temperature and external demagnetizing fields are easiest to calculate on NdFeB magnets that may be demagnetized as a result of such exposure if cgs units are used (Gauss, Tesla, MGOe) as cgs units allow faster production of new BH curves. When a new Intrinsic BH curve for Neodymium has been calculated (due to demagnetisation), at any point on the Intrinsic curve, note the corresponding value of H in Oersted and remove it from the corresponding B (in Gauss) of the Intrinsic curve and the resulting value is that of the value of B on the Normal curve (in Gauss) for the same H value. Using this, the Normal BH curve at different temperatures can be estimated if you already have an accurate ambient temperature BH curve for the “Neo” magnet (although this can be applied to any magnet material). Note the Br and Hci at ambient temperature (20 degrees C). If you want the curve at e.g. 120 degrees C, take the ambient temperature away to get the temperature difference (i.e. 120-20=100 degrees C). Multiply this result by the temperature coefficients to give the percentage changes in Br and Hci to be expected. So Br will drop by 100x-0.12=-12% and Hci will drop by 100*-0.6 = 60%. Translate the Intrinsic BH curve shape so the curve starts and ends at the newly calculated Br and Hci and re-draw the new Intrinsic curve. This is the Intrinsic curve at 120 degrees C. Then use the calculation to convert from Intrinsic to Normal in cgs units for any given H in Oersteds to generate the new Normal curve for the NdFeB. This new BH curve set can then be used for the calculations at 120 degrees C. Please note that this is an estimate as the temperature coefficients actually vary with temperature and the BH curve varies from batch to batch for any magnet, including Neodymium.

Neodymium Iron Boron magnets are a type of rare earth alloy that typically has two atoms of Neodymium (Nd), 14 atoms of Iron (Fe), and one atom of Boron (B) as its primary elements, hence their chemical composition Nd₂Fe₁₄B, which is commonly abbreviated as NdFeB. There are other elements that are used to increase the coercivity, to gain lower oxidation characteristics, and to obtain other desirable characteristics. These elements are used to 'dope' the alloy and are generally found in small quantities (<10% by weight).

Sintered Neodymium Iron Boron Magnets

The sintered Neodymium Iron Boron magnet is produced by the OPS (orient-press-sinter) method. A crystalline alloy of Neodymium, Iron, and Boron is ground to a sub-micron powder using a ball mill, then aligned in a strong magnetic field, and pressed into a basic shape. The resultant 'block' is then sintered, thereby fusing the material into a solid metal.

Generally, Neodymium Iron Boron magnets are sensitive to changes in temperature (reversible temperature coefficients being around -0.13%/°C). Additionally, they are more prone to oxidation than any other magnet alloy. Coating or plating is generally recommended unless using advanced alloys, such as MCE'sN3080, N3275, and N4467. MCE's advanced grades are developed specifically for applications where the application of coating or plating is not desired. These advanced grades have oxidation rates that are far below the average Neodymium Iron Boron alloys, making them ideal for applications that require post assembly processing, due to tight tolerances in the final assembly state.

Ndfeb 52

Neodymium Iron Boron magnets have some advantages over Samarium Cobalt magnets. Neodymium Iron Boron magnets are less expensive, since the main elements Nd and Fe are abundant, and are mechanically stronger. High energy products can be achieved. Small production runs have successfully yielded 58 MGOe nominal energy products; however, these are only achievable in the R&D state. Neodymium Iron Boron magnets are about 13% lighter than SmCo magnets. However, before deciding which material is better for you, review the comparisons between Neodymium Iron Boron and Samarium Cobalt.

Over the last 10 years, Neodymium Iron Boron magnets have become extremely popular in almost all high technology applications that require high performance magnets. Motors, sensors, computers, and microwave components are a few areas where Neodymium Iron Boron magnets are successfully used . The recent 'miniaturization' of electronic and mechanical components is due to the high-energy products that are achieved using Neodymium Iron Boron magnets. Large capacity hard drives, miniature hand held tape recorders, feather weight head sets, and anti-lock braking systems have made tremendous leaps due to the Neodymium magnets.

The selection of Neodymium Iron Boron magnets in your applications will depend on your working environment. If you use the magnets at elevated temperatures, select the alloys that have a high intrinsic coercivity (Hci). If you use the alloy at lower temperatures (such as room temperature), you may select higher Br materials. Remember that if the magnet is being used in adverse conditions, such as repelling positions in motors where repelling magnetic fields are being used to drive the rotor and similar applications, selecting materials with moderate or high coercivity is recommended. Applications where fields are being used to trigger sensors, switches, and similar applications may use lower coercivity magnets.

Using the Neodymium Iron Boron magnet in cryogenic temperatures (below 200°C) is not recommended.

Since the Neodymium Iron Boron magnets are prone to rapid oxidation, salt spray, salt water, and hydrogen are very harsh on the magnet. Consider hermetically sealing the magnet if you wish to use NdFeB in such environments. For high reliability applications, familiarize yourself with the section 'testing and certification' so that you understand the tests that are available. Some of these tests are used to predict how the magnet will perform over extended periods in the field.

MCE offers the world's premium Neodymium Iron Boron alloys, advanced coatings, and the ability to provide fast production runs. Additionally, MCE can manufacture and fabricate entire assemblies, such as rotor or stator assemblies, couplings, and hermetically sealed components to your requirements.

Bonded Neodymium Iron Boron Magnets

The bonded Neodymium Iron Boron materials are typically anisotropic. They can be made isotropic, and are manufactured using 'binders,' such as epoxy resins or nylon to hold the powder in place, rather than 'sintering' the alloy. Energy products of the bonded magnet range from 5 MGOe to 10 MGOe. Two basic processes are used:

Ndfeb Cte

1. Compression Molding Binders are epoxy resins, and energy products of 10 MGOe are achievable. Moderately complex shapes can be achieved.
   
2. Injection Molding Binders are generally nylon, but epoxy resins may also be used. Energy products are lower than compression molding; however, more complex shapes can be achieved without final processing, which makes it cost effective for low to medium performance applications which are cost sensitive.

Ndfeb Density

The bonded Neodymium Iron Boron magnet may be used without surface treatment; however, coating is recommended. Generally, spray coatings are used, such has phenolic or epoxy coating.

A word of caution:

Do NOT use Neodymium Iron Boron magnets under the following conditions:

• In an acidic, alkaline, or organic solvent (unless you are going to hermetically seal the magnet inside a can)
• In water or oil (unless hermetically sealed, or you are prepared to accept a limited life)
• In an electrically conductive liquid, such as electrolyte containing water
• In a hydrogen-containing atmosphere, especially at elevated temperatures. Hydrogenation, a process where the Hydrogen molecule will react with the NdFeB, will occur, causing the magnet to rapidly deteriorate
• Environments containing corrosive gasses, such as Cl, NH3, Nox, etc.
• In the path of radioactive rays